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We present the analysis of cloud–cloud collision (CCC) process in the Galactic molecular complex S235. Our new CO observations performed with the PMO-13.7 m telescope reveal two molecular clouds, namely the S235-Main and the S235-ABC, with ∼4 km s−1 velocity separation. The bridge feature, the possible colliding interface and the complementary distribution of the two clouds are significant observational signatures of cloud–cloud collision in S235. The most direct evidence of cloud–cloud collision process in S235 is that the S235-Main (in a distance of 1547$^{+44}_{-43}$ pc) and S235-ABC (1567$^{+33}_{-39}$ pc) meet at almost the same position (within 1σ error range) at a supersonic relative speed. We identified ten 13CO clumps from PMO-13.7 m observations, 22 dust cores from the archival SCUBA-2 data, and 550 YSOs from NIR–MIR data. 63 per cent of total YSOs are clustering in seven MST groups (M1−M7). The tight association between the YSO groups (M1 $\&$ M7) and the bridge feature suggests that the CCC process triggers star formation there. The collisional impact subregion (the South) shows 3 ∼ 5 times higher CFE and SFE (average value of 12.3 and 10.6 per cent, respectively) than the non-collisional impact subregion (2.4 and 2.6 per cent, respectively), suggesting that the CCC process may have enhanced the CFE and SFE of the clouds compared to those without collision influence.

 

Axially chiral enamides bearing a N–C axis have been recently studied and were proposed to be valuable chiral building blocks, but a stereoselective synthesis has not been achieved. Here, we report the first enantioselective synthesis of axially chiral enamides via a highly efficient, catalytic approach. In this approach, C(sp 2 )–N bond formation is achieved through an iridium-catalyzed asymmetric allylation, and then in situ isomerization of the initial products through an organic base promoted 1,3-H transfer, leading to the enamide products with excellent central-to-axial transfer of chirality. Computational and experimental studies revealed that the 1,3-H transfer occurs via a stepwise deprotonation/re-protonation pathway with a chiral ion-pair intermediate. Hydrogen bonding interactions with the enamide carbonyl play a significant role in promoting both the reactivity and stereospecificity of the stepwise 1,3-H transfer. The mild and operationally simple formal N -vinylation reaction delivered a series of configurationally stable axially chiral enamides with good to excellent yields and enantioselectivities. 

Determining the nature and age of the 200-km-wide Chicxulub impact target rock is an essential step in advancing our understanding of the Maya Block basement. Few age constraints exist for the northern Maya Block crust, specifically the basement underlying the 66 Ma, 200 km-wide Chicxulub impact structure. The International Ocean Discovery Program-International Continental Scientific Drilling Program Expedition 364 core recovered a continuous section of basement rocks from the Chicxulub target rocks, which provides a unique opportunity to illuminate the pre-impact tectonic evolution of a terrane key to the development of the Gulf of Mexico. Sparse published ages for the Maya Block point to Mesoproterozoic, Ediacaran, Ordovician to Devonian crust are consistent with plate reconstruction models. In contrast, granitic basement recovered from the Chicxulub peak ring during Expedition 364 yielded new zircon U-Pb laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) concordant dates clustering around 334 ± 2.3 Ma. Zircon rare earth element (REE) chemistry is consistent with the granitoids having formed in a continental arc setting. Inherited zircon grains fall into three groups: 400−435 Ma, 500−635 Ma, and 940−1400 Ma, which are consistent with the incorporation of Peri-Gondwanan, Pan-African, and Grenvillian crust, respectively. Carboniferous U-Pb ages, trace element compositions, and inherited zircon grains indicate a pre-collisional continental volcanic arc located along the Maya Block’s northern margin before NW Gondwana collided with Laurentia. The existence of a continental arc along NW Gondwana suggests southward-directed subduction of Rheic oceanic crust beneath the Maya Block and is similar to evidence for a continental arc along the northern margin of Gondwana that is documented in the Suwannee terrane, Florida, USA, and Coahuila Block of NE México. 

The ~180-km-diameter Chicxulub peak-ring crater and ~240-km multiring basin, produced by the impact that terminated the Cretaceous, is the largest remaining intact impact basin on Earth. International Ocean Discovery Program (IODP) and International Continental Scientific Drilling Program (ICDP) Expedition 364 drilled to a depth of 1335 m below the sea floor into the peak ring, providing a unique opportunity to study the thermal and chemical modification of Earth’s crust caused by the impact. The recovered core shows the crater hosted a spatially extensive hydrothermal system that chemically and mineralogically modified ~1.4 × 10 5 km 3 of Earth’s crust, a volume more than nine times that of the Yellowstone Caldera system. Initially, high temperatures of 300° to 400°C and an independent geomagnetic polarity clock indicate the hydrothermal system was long lived, in excess of 10 6 years.